Surface functionalization of metal-organic polyhedron for homogeneous cyclopropanation catalysis

被引：97

作者：

Lu, Weigang ^{[1
]}

Yuan, Daqiang ^{[1
]}

Yakovenko, Andrey ^{[1
]}

Zhou, Hong-Cai ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 17期

基金：

美国国家科学基金会;

关键词：

HYDROXYLATED NANOBALLS; CRYSTAL-STRUCTURE; FRAMEWORKS; CHEMISTRY; LIGANDS;

D O I：

10.1039/c1cc00030f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A super-paddlewheel (comprised of two paddlewheels) metal-organic polyhedron (MOP) containing surface hydroxyl groups was synthesized and characterized. Condensation reactions with linear alkyl anhydrides lead to new MOPs with enhanced solubility. As a result, the surface-modified MOP 4 was demonstrated as a homogeneous Lewis-acid catalyst.

引用

收藏

页码：4968 / 4970

页数：3

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