Cu2+-Mediated dehydrogenative coupling and hydroxylation of an N-heterocyclic ligand:: From generation of a new tetratopic ligand to the designed assembly of three-dimensional copper(I) coordination polymers

被引：195

作者：

Hu, S

Chen, JC

Tong, ML ^{[1
]}

Wang, B

Yan, YX

Batten, SR

机构：

[1] Sun Yat Sen Univ, Sch Chem & Chem Engn, Inst Optoelect & Funct Composite Mat, Guangzhou 510275, Peoples R China

[2] Sun Yat Sen Univ, Sch Chem & Chem Engn, State Key Lab Optoelect Mat & Technol, Guangzhou 510275, Peoples R China

[3] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 34期

关键词：

copper; hydrothermal synthesis; N ligands; organic-inorganic hybrid composites; topochemistry;

D O I：

10.1002/anie.200501753

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) The hydrothermal reaction of 1,3-di(4-pyridyl)propane with Cu(OH)2 in the presence of 1,4-cyclohexanedicarboxylic acid and dilute HCl generates an unprecedented tetratopic ligand (chtpy) and a family of interesting coordination networks in situ (see scheme). The topological diversification of the CuI-chtpy nets can be controlled simply by changing the molar ratio of the starting materials. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：5471 / 5475

页数：5

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