Graphite oxide as an efficient and durable metal-free catalyst for aerobic oxidative coupling of amines to imines

被引:222
作者
Huang, Hai [1 ]
Huang, Jun [1 ]
Liu, Yong-Mei [1 ]
He, He-Yong [1 ]
Cao, Yong [1 ]
Fan, Kang-Nian [1 ]
机构
[1] Fudan Univ, Dept Chem, Shanghai Key Lab Mol Catalysis & Innovat Mat, Shanghai 200433, Peoples R China
基金
中国国家自然科学基金;
关键词
SUPPORTED GOLD NANOPARTICLES; REDUCED GRAPHENE OXIDE; DEHYDROGENATIVE OXIDATION; ACTIVE CATALYSTS; SECONDARY-AMINES; ONE-POT; ALCOHOLS; CARBON; SURFACE; HYDROXYAPATITE;
D O I
10.1039/c2gc16681j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Graphite oxide was found to be a highly efficient, reusable and cost-effective heterogeneous catalyst for the direct metal-free transformation of amines to afford the corresponding imines under mild and neat conditions with molecular oxygen as the terminal oxidant. This method is simple, economic and environmentally benign, resulting in practical advantages for the convenient synthesis of imines and their derivatives.
引用
收藏
页码:930 / 934
页数:5
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