Pinwheel motifs:: formation of unusual homo- and hetero-nuclear aggregates via bridging thiolates

被引:25
作者
Amoroso, AJ [1 ]
Chung, SSM [1 ]
Spencer, DJE [1 ]
Danks, JP [1 ]
Glenny, MW [1 ]
Blake, AJ [1 ]
Cooke, PA [1 ]
Wilson, C [1 ]
Schröder, M [1 ]
机构
[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England
关键词
D O I
10.1039/b303851c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The homohexanuclear complexes [Ni-2{Ni(L-1)}(4)](BF4)(4).MeCN, 1, [Pd-2{Pd(L-2)}(4)](BF4)(4), 2, and the heteropentanuclear aggregate [Cu-2{Ni(L-3)}(3)](PF6)(2), 3, all adopt a 'pin-wheel' type structural motif via thiolate bridging between square-planar Ni(II) or Pd(II) and between trigonal planar Cu(I) centres, respectively.
引用
收藏
页码:2020 / 2021
页数:2
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