Sugar-sensing by chiral orientation of dimeric boronic-acid-appended porphyrins which show selectivity for glucose and xylose

被引：31

作者：

Arimori, S ^{[1
]}

Takeuchi, M ^{[1
]}

Shinkai, S ^{[1
]}

机构：

[1] KYUSHU UNIV, FAC ENGN, DEPT CHEM SCI & TECHNOL, FUKUOKA 812, JAPAN

来源：

CHEMISTRY LETTERS | 1996年 / 01期

关键词：

D O I：

10.1246/cl.1996.77

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

5,10,15,20-Tetrakis(4-boronylphenyl)porphyrin (1) and 5, 10,15,20-tetrakis[N-(2- or 4-boronylphenyl)methyl-pyridinium] porphyrin (o-2 or p-2) formed a 1:1 complex, which gave specific exciton-coupling bands in CD spectroscopy only in the presence of glucose and xylose among monosaccharides. The structural examination established that only these monosaccharides can bridge two porphyrins by covalent-bond formation with boronic acids and twist them asymmetrically.

引用

页码：77 / 78

页数：2

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