The electrophilic nature of carbenoids, nitrenoids, and oxenoids

被引：300

作者：

Boche, G ^{[1
]}

Lohrenz, JCW ^{[1
]}

机构：

[1] Univ Marburg, Fachbereich Chem, D-35032 Marburg, Germany

来源：

CHEMICAL REVIEWS | 2001年 / 101卷 / 03期

关键词：

D O I：

10.1021/cr940260x

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The electrophilic properties of carbenoids, nitrenoids and oxenoids were investigated. An analysis of their chemical bonds and atomic orbitals was performed and quantum chemical calculations supported the nature of these compounds. A metal and a leaving group, bonded simultaneously to a carbon, nitrogen or oxygen atom resulted in the characteristic properties of the compounds.

引用

页码：697 / 756

页数：60

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