The electrophilic nature of carbenoids, nitrenoids, and oxenoids

被引:303
作者
Boche, G [1 ]
Lohrenz, JCW [1 ]
机构
[1] Univ Marburg, Fachbereich Chem, D-35032 Marburg, Germany
关键词
D O I
10.1021/cr940260x
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The electrophilic properties of carbenoids, nitrenoids and oxenoids were investigated. An analysis of their chemical bonds and atomic orbitals was performed and quantum chemical calculations supported the nature of these compounds. A metal and a leaving group, bonded simultaneously to a carbon, nitrogen or oxygen atom resulted in the characteristic properties of the compounds.
引用
收藏
页码:697 / 756
页数:60
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