The catalytic nanodiode: Gas phase catalytic reaction generated electron flow using nanoscale platinum titanium oxide Schottky diodes

被引:57
作者
Ji, XZ
Zuppero, A
Gidwani, JM
Somorjai, GA [1 ]
机构
[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
[2] NeoKismet LCC, San Francisco, CA 94104 USA
关键词
D O I
10.1021/nl050241a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Forty microampere current was generated on a platinum-titanium dioxide Schottky diode during the platinum catalyzed steady-state oxidation of carbon monoxide at 80 degrees C. For reaction events that produced four CO2 molecules, three injected electrons were collected in a diode comprising a 5 nm thick platinum and a 150 nm titanium dioxide film. The electron injection flux depends on the thickness of the platinum and the titanium dioxide diode properties as well as the conditions of the catalytic reactions.
引用
收藏
页码:753 / 756
页数:4
相关论文
共 11 条
[1]   NONADIABATIC SURFACE-REACTION - MECHANISM OF ELECTRON-EMISSION IN THE CS+O-2 SYSTEM [J].
BOTTCHER, A ;
IMBECK, R ;
MORGANTE, A ;
ERTL, G .
PHYSICAL REVIEW LETTERS, 1990, 65 (16) :2035-2037
[2]  
GERGEN B, 2002, THESIS U CALIFORNIA
[3]   ELECTRON-TRANSFER PATHWAYS IN DYNAMIC PROCESSES - CL-2 ON K [J].
HELLBERG, L ;
STROMQUIST, J ;
KASEMO, B ;
LUNDQVIST, BI .
PHYSICAL REVIEW LETTERS, 1995, 74 (23) :4742-4745
[4]   Vibrational promotion of electron transfer [J].
Huang, YH ;
Rettner, CT ;
Auerbach, DJ ;
Wodtke, AM .
SCIENCE, 2000, 290 (5489) :111-114
[5]   DESORPTION OF CARBON-DIOXIDE MOLECULES FROM A PT(111) SURFACE - A STOCHASTIC CLASSICAL TRAJECTORY APPROACH [J].
KWONG, DWJ ;
DELEON, N ;
HALLER, GL .
CHEMICAL PHYSICS LETTERS, 1988, 144 (5-6) :533-540
[6]   The role of carbon deposition from CO dissociation on platinum crystal surfaces during catalytic CO oxidation: Effects on turnover rate, ignition temperature, and vibrational spectra [J].
McCrea, KR ;
Parker, JS ;
Somorjai, GA .
JOURNAL OF PHYSICAL CHEMISTRY B, 2002, 106 (42) :10854-10863
[7]  
Nienhaus H, 2002, SURF SCI REP, V45, P3, DOI 10.1016/S0167-5729(01)00019-X
[8]   Carbon monoxide oxidation over three different oxidation states of copper: Metallic copper, copper (I) oxide, and copper (II) oxide - A surface science and kinetic study - Response [J].
Somorjai, GA ;
Jernigan, G .
JOURNAL OF CATALYSIS, 1997, 165 (02) :284-284
[9]   High-pressure CO oxidation on Pt(111) monitored with infrared-visible sum frequency generation (SFG) [J].
Su, XC ;
Cremer, PS ;
Shen, YR ;
Somorjai, GA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (17) :3994-4000
[10]   THE OSCILLATORY BEHAVIOR OF THE CO OXIDATION REACTION AT ATMOSPHERIC-PRESSURE OVER PLATINUM SINGLE-CRYSTALS - SURFACE-ANALYSIS AND PRESSURE DEPENDENT MECHANISMS [J].
YEATES, RC ;
TURNER, JE ;
GELLMAN, AJ ;
SOMORJAI, GA .
SURFACE SCIENCE, 1985, 149 (01) :175-190