Synthetic studies towards gambierol. Part 2: Synthesis of the EFGH ring segment

被引：17

作者：

Kadota, I

Kadowaki, C

Takamura, H

Yamamoto, Y ^{[1
]}

机构：

[1] Tohoku Univ, Dept Chem, Grad Sch Sci, Sendai, Miyagi 9808578, Japan

[2] Tohoku Univ, Res Ctr Sustainable Mat Engn, Inst Multidisciplinary Res Adv Mat, Sendai, Miyagi 9808578, Japan

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 35期

关键词：

D O I：

10.1016/S0040-4039(01)01205-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The EFGH ring segment of gambierol was synthesized from 2-deoxy-D-ribose in 40 steps. The present synthesis includes a SmI2-mediated reductive cyclization and a Pd-catalyzed coupling of enot triflate with a zinc bis-homoenolate as key steps. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：6199 / 6202

页数：4

共 17 条

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