Shape-selective hydrogenation and hydrogen transfer reactions over zeolite catalysts

被引：49

作者：

Creyghton, EJ ^{[1
]}

Downing, RS ^{[1
]}

机构：

[1] Delft Univ Technol, Organ Chem & Catalysis Lab, NL-2628 BL Delft, Netherlands

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1998年 / 134卷 / 1-3期

关键词：

zeolite; shape-selectivity; hydrogenation; hydrogen transfer; Meerwein-Ponndorf-Verley reduction; metal cluster; metal complex;

D O I：

10.1016/S1381-1169(98)00022-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A review of the application of zeolite systems in shape-selective hydrogenation and hydrogen transfer reactions is presented. Two different types of catalytic systems are discussed. The first consists of metal clusters or coordination complexes encapsulated in the micropores of a zeolite employing hydrogen as the reductant. Recent developments, such as the application of zeolite-containing composite catalysts are included. In the second system, zeolites are applied as catalyst in hydrogen-transfer reactions using a secondary alcohol as hydrogen donor in the Meerwein-Ponndorf-Verley reduction. (C) 1998 Elsevier Science B.V. All rights reserved.

引用

页码：47 / 61

页数：15

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