From supported homogeneous catalysts to heterogeneous molecular catalysts

被引：155

作者：

Choplin, A ^{[1
]}

Quignard, F ^{[1
]}

机构：

[1] Univ Lyon 1, CNRS, Inst Rech Catalyse, F-69626 Villeurbanne, France

来源：

COORDINATION CHEMISTRY REVIEWS | 1998年 / 178卷

关键词：

anchored catalysts; heterogeneous molecular catalysts; heterogeneous molecularly dispersed catalysts; immobilized catalysts; supported homogeneous catalysts;

D O I：

10.1016/S0010-8545(98)00062-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Numerous methods are now available for the synthesis of a large variety of heterogeneous molecular catalysts. Their specific domain of application, and the main advantages and drawbacks of these solids are briefly analyzed here. (C) 1998 Elsevier Science S.A. All rights reserved.

引用

页码：1679 / 1702

页数：24

共 146 条

[31] SPECTROSCOPIC STUDIES ON ADSORBED METAL-CARBONYLS .3. INTERACTION OF [OS3(CO)12] WITH SILICA, ALUMINA, AND TITANIA [J].

COOK, SL ;

EVANS, J ;

MCNULTY, GS ;

GREAVES, GN .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1986, (01) :7-14

[32] CATALYTIC DEHYDROGENATIVE COUPLING OF SECONDARY SILANES WITH CP2MCL2/NORMAL-BULI [J].

COREY, JY ;

ZHU, XH ;

BEDARD, TC ;

LANGE, LD .

ORGANOMETALLICS, 1991, 10 (04) :924-930

[33] INTRODUCING TPPTS AND RELATED LIGANDS FOR INDUSTRIAL BIPHASIC PROCESSES [J].

CORNILS, B ;

KUNTZ, EG .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1995, 502 (1-2) :177-186

[34] H/D EXCHANGE OF ORGANOSILANES CATALYZED BY HETEROGENIZED ZIRCONIUM HYDRIDE COMPLEXES [J].

COUTANT, B ;

QUIGNARD, F ;

CHOPLIN, A .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (02) :137-138

[35] THE ORGANOMETALLIC CHEMISTRY OF ALKANES [J].

CRABTREE, RH .

CHEMICAL REVIEWS, 1985, 85 (04) :245-269

[36] A SUPPORTED TRIOSMIUM CLUSTER CATALYST - EVIDENCE FOR METAL-METAL BONDS FROM LASER RAMAN-SPECTROSCOPY [J].

DEEBA, M ;

STREUSAND, BJ ;

SCHRADER, GL ;

GATES, BC .

JOURNAL OF CATALYSIS, 1981, 69 (01) :218-221

[37] MEERWEIN-PONNDORF-VERLEY REDUCTIONS AND OPPENAUER OXIDATIONS - AN INTEGRATED APPROACH [J].

DEGRAAUW, CF ;

PETERS, JA ;

VANBEKKUM, H ;

HUSKENS, J .

SYNTHESIS-STUTTGART, 1994, (10) :1007-1017

[38] GAS-PHASE HYDROFORMYLATION OF PROPYLENE WITH POROUS RESIN ANCHORED RHODIUM COMPLEXES .2. THE CATALYTIC PERFORMANCE [J].

DEMUNCK, NA ;

VERBRUGGEN, MW ;

DELEUR, JE ;

SCHOLTEN, JJF .

JOURNAL OF MOLECULAR CATALYSIS, 1981, 11 (2-3) :331-342

[39] 3-CHLOROPROPYLTRIALKOXYSILANES - KEY INTERMEDIATES FOR THE COMMERCIAL PRODUCTION OF ORGANOFUNCTIONALIZED SILANES AND POLYSILOXANES [J].

DESCHLER, U ;

KLEINSCHMIT, P ;

PANSTER, P .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1986, 25 (03) :236-252

[40]

DORNELAS L, 1985, NEW J CHEM, V9, P655

← 1 2 3 4 5 6 7 8 9 10 →