From supported homogeneous catalysts to heterogeneous molecular catalysts

被引：155

作者：

Choplin, A ^{[1
]}

Quignard, F ^{[1
]}

机构：

[1] Univ Lyon 1, CNRS, Inst Rech Catalyse, F-69626 Villeurbanne, France

来源：

COORDINATION CHEMISTRY REVIEWS | 1998年 / 178卷

关键词：

anchored catalysts; heterogeneous molecular catalysts; heterogeneous molecularly dispersed catalysts; immobilized catalysts; supported homogeneous catalysts;

D O I：

10.1016/S0010-8545(98)00062-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Numerous methods are now available for the synthesis of a large variety of heterogeneous molecular catalysts. Their specific domain of application, and the main advantages and drawbacks of these solids are briefly analyzed here. (C) 1998 Elsevier Science S.A. All rights reserved.

引用

页码：1679 / 1702

页数：24

共 146 条

[51] HYDROFORMYLATION WITH SUPPORTED LIQUID-PHASE RHODIUM CATALYSTS .3. INFLUENCE OF THE TYPE OF SUPPORT, THE DEGREE OF PORE FILLING AND ORGANIC ADDITIVES ON THE CATALYTIC PERFORMANCE [J].

GERRITSEN, LA ;

HERMAN, JM ;

SCHOLTEN, JJF .

JOURNAL OF MOLECULAR CATALYSIS, 1980, 9 (03) :241-256

[52] TITANACYCLOBUTANES DERIVED FROM STRAINED CYCLIC OLEFINS - THE LIVING POLYMERIZATION OF NORBORNENE [J].

GILLIOM, LR ;

GRUBBS, RH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (04) :733-742

[53]

GOU I, 1991, J ORGANOMET CHEM, V403, P221

[54]

GOU I, 1991, J MOL CATAL, V70, P363

[55] THE ACTIVATION OF CARBON-HYDROGEN BONDS [J].

GREEN, MLH ;

OHARE, D .

PURE AND APPLIED CHEMISTRY, 1985, 57 (12) :1897-1910

[56] SPECTROSCOPIC STUDY OF THE ADSORPTION AND VACUUM DECARBONYLATION OF FE(CO)5 ON MGO [J].

GUGLIELMINOTTI, E ;

ZECCHINA, A .

JOURNAL OF MOLECULAR CATALYSIS, 1984, 24 (03) :331-344

[57]

HAAG WA, 1969, Patent No. 1800371

[58] THE STRUCTURE OF SURFACE RHENIUM OXIDE ON ALUMINA FROM LASER RAMAN-SPECTROSCOPY AND X-RAY ABSORPTION NEAR-EDGE SPECTROSCOPY [J].

HARDCASTLE, FD ;

WACHS, IE ;

HORSLEY, JA ;

VIA, GH .

JOURNAL OF MOLECULAR CATALYSIS, 1988, 46 (1-3) :15-36

[59] CATALYTIC DEHYDROCOUPLING - A GENERAL-METHOD FOR THE FORMATION OF ELEMENT-ELEMENT BONDS [J].

HARROD, JF ;

MU, Y ;

SAMUEL, E .

POLYHEDRON, 1991, 10 (11) :1239-1245

[60]

HARTLEY FR, 1985, SUPPERTED METAL COMP

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