A comprehensive model for bipolar electrical switching of CuTCNQ memories

被引:59
作者
Billen, J. [1 ,2 ]
Steudel, S. [1 ]
Muller, R. [1 ]
Genoe, J. [1 ]
Heremans, P. [1 ,2 ]
机构
[1] IMEC VZW, B-3001 Louvain, Belgium
[2] Katholieke Univ Leuven, Dept ESAT, B-3001 Louvain, Belgium
关键词
D O I
10.1063/1.2827590
中图分类号
O59 [应用物理学];
学科分类号
摘要
The generally observed bipolar electrical switching of Cu\CuTCNQ\metal memories (metal=Al,Yb,Ti) between two stable resistance states is shown to occur at the CuTCNQ\metal interface and not in the bulk of CuTCNQ. The switching is explained by a model involving electrochemical formation and dissolution of Cu filaments at the interface. In this mechanism, CuTCNQ acts as solid ionic conductor and source for the Cu+ cations. The model also explains earlier reported findings of bipolar switching in CuTCNQ devices, including the apparently contradictory observation that neutral TCNQ appears in the low-resistance state. (c) 2007 American Institute of Physics.
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页数:3
相关论文
共 25 条
[1]  
[Anonymous], 2001, RIKEN REV
[2]  
BAGOTSKY VS, 2005, FUNDAMENTALS ELECTRO, P136
[3]  
BILLEN J, 2007, P 2 INT C MEM TECHN, P135
[4]   Switching and filamentary conduction in non-volatile organic memories [J].
Colle, Michael ;
Buchel, Michael ;
de Leeuw, Dago M. .
ORGANIC ELECTRONICS, 2006, 7 (05) :305-312
[5]   New insight into the nature of Cu(TCNQ): Solution routes to two distinct polymorphs and their relationship to crystalline films that display bistable switching behavior [J].
Heintz, RA ;
Zhao, HH ;
Xiang, OY ;
Grandinetti, G ;
Cowen, J ;
Dunbar, KR .
INORGANIC CHEMISTRY, 1999, 38 (01) :144-156
[6]   CHARACTERIZATION OF CU-CUTCNQ-M DEVICES USING SCANNING ELECTRON-MICROSCOPY AND SCANNING TUNNELING MICROSCOPY [J].
HOAGLAND, JJ ;
WANG, XD ;
HIPPS, KW .
CHEMISTRY OF MATERIALS, 1993, 5 (01) :54-60
[7]   A nonvolatile programmable solid-electrolyte nanometer switch [J].
Kaeriyama, S ;
Sakamoto, T ;
Sunamura, H ;
Mizuno, M ;
Kawaura, H ;
Hasegawa, T ;
Terabe, K ;
Nakayama, T ;
Aono, M .
IEEE JOURNAL OF SOLID-STATE CIRCUITS, 2005, 40 (01) :168-176
[8]   RAMAN-STUDY OF THE MECHANISM OF ELECTRICAL SWITCHING IN CU TCNQ FILMS [J].
KAMITSOS, EI ;
TZINIS, CH ;
RISEN, WM .
SOLID STATE COMMUNICATIONS, 1982, 42 (08) :561-565
[9]   On the origin of bistable resistive switching in metal organic charge transfer complex memory cells [J].
Kever, T. ;
Boettger, U. ;
Schindler, C. ;
Waser, R. .
APPLIED PHYSICS LETTERS, 2007, 91 (08)
[10]   Preparation and characterisation of amorphous Cu:7,7,8,8-Tetracyanoquinodimethane thin films with low surface roughness via thermal co-deposition [J].
Kever, Thorsten ;
Nauenheim, Christian ;
Boettger, Ulrich ;
Waser, Rainer .
THIN SOLID FILMS, 2006, 515 (04) :1893-1896