Catalytic asymmetric hydroamination of non-activated olefins

被引：196

作者：

Hultzsch, KC ^{[1
]}

机构：

[1] Univ Erlangen Nurnberg, Inst Organ Chem, D-91054 Erlangen, Germany

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2005年 / 3卷 / 10期

关键词：

D O I：

10.1039/b418521h

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Hydroamination is a highly atom-economical process in which an amine N-H functionality is added to an unsaturated carbon-carbon linkage. This potentially highly useful process gives access to various nitrogen-containing basic and. ne chemicals as well as naturally occurring alkaloid skeletons. Asymmetric hydroamination reactions promoted by chiral catalysts are particularly attractive. This review highlights recent progress in the development of early transition metal catalysts for the asymmetric hydroamination of non-activated alkenes.

引用

页码：1819 / 1824

页数：6

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