Will we soon be fueling our automobiles with ammonia-borane?

被引：562

作者：

Marder, Todd B. ^{[1
]}

机构：

[1] Univ Durham, Dept Chem, Durham DH1 3LE, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 43期

关键词：

boron; hydrogen storage; sustainable chemistry;

D O I：

10.1002/anie.200703150

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) The B all and N all? Ammonia-borane (AB, H 3NBH3) contains 19.6 weight % H1 and is one of the materials currently being examined as a possible H2 source for use in fuel cells to power automobiles. Challenges for this technology are noted, and recent advances, especially in the development of both transition-metal and acid catalysts which promote H2 release from AB under mild conditions, are highlighted. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

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页码：8116 / 8118

页数：3

相关论文

共 34 条

[1]

[Anonymous], ANGEW CHEM

[2]

BAKER RT, 2007, FY2007 DOE

[3] Thermal decomposition of polymeric aminoborane (H2BNH2)x under hydrogen release [J].

Baumann, J ;

Baitalow, E ;

Wolf, G .

THERMOCHIMICA ACTA, 2005, 430 (1-2) :9-14

[4] Amineborane-based chemical hydrogen storage: Enhanced ammonia borane dehydrogenation in ionic liquids [J].

Bluhm, Martin E. ;

Bradley, Mark G. ;

Butterick, Robert, III ;

Kusari, Upal ;

Sneddon, Larry G. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (24) :7748-7749

[5] Dissociation and hydrolysis of ammonia-borane with solid acids and carbon dioxide: An efficient hydrogen generation system [J].

Chandra, Manish ;

Xu, Qiang .

JOURNAL OF POWER SOURCES, 2006, 159 (02) :855-860

[6] A high-performance hydrogen generation system: Transition metal-catalyzed dissociation and hydrolysis of ammonia-borane [J].

Chandra, Manish ;

Xu, Qiang .

JOURNAL OF POWER SOURCES, 2006, 156 (02) :190-194

[7] In situ XAFS and NMR study of rhodium-catalyzed dehydrogenation of dimethylamine borane [J].

Chen, YS ;

Fulton, JL ;

Linehan, JC ;

Autrey, T .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (10) :3254-3255

[8] Homogeneous, titanocene-catalyzed dehydrocoupling of amine-borane adducts [J].

Clark, Timothy J. ;

Russell, Christopher A. ;

Manners, Ian .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (30) :9582-9583

[9] Transition-metal-catalyzed dehydrocoupling: A convenient route to bonds between main-group elements [J].

Clark, Timothy J. ;

Lee, Kajin ;

Manners, Ian .

CHEMISTRY-A EUROPEAN JOURNAL, 2006, 12 (34) :8634-8648

[10] The hydrogen economy [J].

Crabtree, GW ;

Dresselhaus, MS ;

Buchanan, MV .

PHYSICS TODAY, 2004, 57 (12) :39-44

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