Synthesis and electronic structure of a ferroborirene

被引：56

作者：

Braunschweig, Holger

Fernandez, Israel

Frenking, Gernot

Radacki, Krzysztof

Seeler, Fabian

机构：

[1] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany

[2] Univ Marburg, Fachbereich Chem, D-35043 Marburg, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 27期

基金：

中国国家自然科学基金;

关键词：

borirenes; boron; boryl complexes; borylene complexes; density functional calculations;

D O I：

10.1002/anie.200700382

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) The photochemically induced transfer of a ferroborylene yielded the first metal-bound borirene (see scheme and product structure, in which the methyl substituents are omitted). Experimental and theoretical data suggest significant it derealization in the three-membered BC2 ring. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：5215 / 5218

页数：4

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