Efficient one-pot synthesis of propargylstannanes from propargylic alcohol derivatives via allenyltitaniums

被引：13

作者：

An, DK ^{[1
]}

Okamoto, S ^{[1
]}

Sato, F ^{[1
]}

机构：

[1] Tokyo Inst Technol, Dept Biomol Engn, Midori Ku, Yokohama, Kanagawa 2268501, Japan

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 27期

关键词：

tin and compounds; titanium and compounds; alcohols; carbonates;

D O I：

10.1016/S0040-4039(98)00922-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Successive treatment of propargylic carbonates with a Ti(O-i-Pr)(4)/2i-PrMgCl reagent and Bu3SnCl afforded propargylstannanes in excellent yields, thus opening up an easy access to a variety of propargylstannanes, including those containing functional groups such as halide, carbonate and acetal. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：4861 / 4864

页数：4

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