Synthesis of a chiral pyridylphosphine ligand and a comparison of its rhodium complex with the structurally similar arylphosphine rhodium catalysts in the asymmetric hydrogenation of 2-(6′-methoxy-2′-naphthyl)propenoic acid

被引：22

作者：

Hu, WH

Pai, CC

Chen, CC

Xue, GP

Chan, ASC ^{[1
]}

机构：

[1] Hong Kong Polytech Univ, Union Lab Asymmetr Synth, Hong Kong, Peoples R China

[2] Hong Kong Polytech Univ, Dept Appl Biol & Chem Technol, Hong Kong, Peoples R China

来源：

TETRAHEDRON-ASYMMETRY | 1998年 / 9卷 / 18期

关键词：

D O I：

10.1016/S0957-4166(98)00335-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A chiral pyridylphosphine ligand (2R,4R)-2,4-bis[di-3'-(2',6'-dimethoxypyridyl)phosphino]pentane was synthesized. The rhodium catalyzed asymmetric hydrogenation of 2-(6'-methoxy-2'-naphthyl)propenoic acid was studied by using this ligand in comparison with the structurally similar Skewphos analogs. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：3241 / 3246

页数：6

共 9 条

[1]

BRUNNER H, 1995, SYNTHESIS-STUTTGART, P36

[2] New rhodium pyridylphosphine complexes and their application in hydrogenation reactions [J].