A sensitive colorimetric and fluorescent probe based on a polythiophene derivative for the detection of ATP

被引:308
作者
Li, C [1 ]
Numata, M [1 ]
Takeuchi, M [1 ]
Shinkai, S [1 ]
机构
[1] Kyushu Univ, Grad Sch Engn, Dept Chem & Biochem, Fukuoka 8128581, Japan
关键词
aggregation; anion binding; fluorescence; polymers; UV/Vis spectroscopy;
D O I
10.1002/anie.200501823
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
From amber to red: The water-soluble polythiophene derivative 1 forms a supramolecular complex with ATP (adenosine triphosphate) through electrostatic and hydrophobic cooperative interactions which results in a color change of the aqueous solution from yellow to pink-red (see photo; AMP/ ADP = adenosine mono-/diphosphate). Besides naked-eye detection of ATP, the detection limit may be extended to 10-8 M by using fluorometry. (Chemical Equation Presented) © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:6371 / 6374
页数:4
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