Organocatalytic, Oxidative, Intramolecular C-H Bond Amination and Metal-free Cross-Amination of Unactivated Arenes at Ambient Temperature

被引：355

作者：

Antonchick, Andrey P. ^{[1
]}

Samanta, Rajarshi ^{[1
]}

Kulikov, Katharina ^{[1
]}

Lategahn, Jonas ^{[1
]}

机构：

[1] Max Planck Inst Mol Physiol, Abt Chem Biol, D-44227 Dortmund, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 37期

关键词：

amination; C-H functionalization; hypervalent compounds; iodine; organocatalysis; HYPERVALENT IODINE CHEMISTRY; CARBON-NITROGEN BONDS; NATURAL-PRODUCTS; ARYL HALIDES; PALLADIUM; COPPER; FUNCTIONALIZATION; SUBSTITUTION; GENERATION; CARBAZOLE;

D O I：

10.1002/anie.201102984

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The twinkling of an I: In a new atom-economical and environmentally friendly organocatalytic method for intramolecular C-H amination, the C-N bond forms at ambient temperature by abstraction of two atoms of hydrogen; only acetic acid and water are formed as by-products. The method has also been extended to the unprecedented metal-free cross-amination of nonactivated arenes. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：8605 / 8608

页数：4

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