Gallium-boron donor-acceptor bonds

被引:85
作者
Hardman, NJ
Power, PP [1 ]
Gorden, JD
Macdonald, CLB
Cowley, AH
机构
[1] Univ Texas, Dept Chem & Biochem, Austin, TX 78712 USA
[2] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA
关键词
D O I
10.1039/b106599h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Examples of compounds with gallium-boron donor-acceptor bonds, HC[MeC(2,6-(Pr2C6H3)-C-i)N](2)Ga-->B(C6F5)(3) 3 and (eta (5)-C5Me5)Ga--->B(C6F5)(3) 4 have been prepared by treatment of the free gallanediyls with B(C6F5)(3); the structures of both compounds were determined by X-ray crystallography.
引用
收藏
页码:1866 / 1867
页数:2
相关论文
共 18 条
  • [1] A Lewis acid adduct of an alanediyl: An aluminum(I)-boron donor-acceptor bond
    Gorden, JD
    Voigt, A
    Macdonald, CLB
    Silverman, JS
    Cowley, AH
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (05) : 950 - 951
  • [2] THE MOLECULAR-STRUCTURE OF PENTAMETHYLCYCLOPENTADIENYLGALLIUM, GA(ETA-C5ME5), BY GAS-PHASE ELECTRON-DIFFRACTION - THE 1ST MONOMERIC ORGANOGALLIUM(I) COMPOUND
    HAALAND, A
    MARTINSEN, KG
    VOLDEN, HV
    LOOS, D
    SCHNOCKEL, H
    [J]. ACTA CHEMICA SCANDINAVICA, 1994, 48 (02): : 172 - 174
  • [3] MOLECULAR-STRUCTURE OF MONOMERIC (PENTAMETHYLCYCLOPENTADIENYL)ALUMINUM(I) BY GAS-PHASE ELECTRON-DIFFRACTION
    HAALAND, A
    MARTINSEN, KG
    SHLYKOV, SA
    VOLDEN, HV
    DOHMEIER, C
    SCHNOCKEL, H
    [J]. ORGANOMETALLICS, 1995, 14 (06) : 3116 - 3119
  • [4] Synthesis and characterization of the monomer Ga{(NDippCMe)2CH} (Dipp = C6H3Pri2-2,6):: a low valent gallium(I) carbene analogue
    Hardman, NJ
    Eichler, BE
    Power, PP
    [J]. CHEMICAL COMMUNICATIONS, 2000, (20) : 1991 - 1992
  • [5] HARDMAN NJ, UNPUB
  • [6] Chemistry of C-trimethylsilyl-substituted heterocarboranes .22. Synthetic, spectroscopic, structural, and bonding studies on half- and full-sandwich gallacarboranes of 2,3- and 2,4-C2B4 carborane ligand systems
    Hosmane, NS
    Lu, KJ
    Zhang, HM
    Maguire, JA
    [J]. ORGANOMETALLICS, 1997, 16 (24) : 5163 - 5170
  • [7] Lewis acid properties of tris(pentafluorophenyl)borane.: Structure and bonding in L-B(C6F5)3 complexes
    Jacobsen, H
    Berke, H
    Döring, S
    Kehr, G
    Erker, G
    Fröhlich, R
    Meyer, O
    [J]. ORGANOMETALLICS, 1999, 18 (09) : 1724 - 1735
  • [8] Cp* Chemistry of main-group elements
    Jutzi, P
    Reumann, G
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (14): : 2237 - 2244
  • [9] Lewis acid-base adducts of pentamethylcyclopentadienylgallium with trivalent group 13-element compounds
    Jutzi, P
    Neumann, B
    Reumann, G
    Schebaum, LO
    Stammler, HG
    [J]. ORGANOMETALLICS, 2001, 20 (13) : 2854 - 2858
  • [10] Synthesis and structure of a tetragallane [R4Ga4I3]- and a polyhedral nonagallane [R6Ga9]-
    Köstler, W
    Linti, G
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1997, 36 (23) : 2644 - 2646