Polyaniline-coated Fe3O4 nanoparticle-carbon-nanotube composite and its application in electrochemical biosensing

被引:170
作者
Liu, Zhun [1 ]
Wang, Joseph [2 ,3 ]
Xie, Donghai [1 ]
Chen, Gang [1 ]
机构
[1] Fudan Univ, Sch Pharm, Shanghai 200032, Peoples R China
[2] Arizona State Univ, Dept Chem & Mat Engn, Tempe, AZ 85287 USA
[3] Arizona State Univ, Dept Chem, Tempe, AZ 85287 USA
基金
美国国家科学基金会;
关键词
biosensors; Fe3O4; glucose; nanocomposites; polyanilines;
D O I
10.1002/smll.200701018
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Well-assembled Polyaniline(PA)-coated Fe3O4 nanoparticle-Carbon-nanotube (CNTs) composites have been prepared by simple two-step deposition approach. Its characterization and application in the electrochemical doping of enzyme for sensing glucose have also been described. CNTs attached to Fe3O4 nanoparticles were coated by a layer of PA to form a novel 1D superparamagnetic conductive material. The solution was stirred mechanically for 10 minutes, after the solution was stirred. CNTs form the cores of the composite and PA acts as the outer cover that protect the nanostructures. A vibrating sample magnetometer was used to record hysteresis loops of Fe3O4-CNT composite in order to characterize the magnetic properties. It was found that the color of Fe 3O4-CNT composite turned brown from black after it was kept in water for 4 days at room temperature.
引用
收藏
页码:462 / 466
页数:5
相关论文
共 35 条
[21]   Carbon nanotubes-iron oxides magnetic composites as adsorbent for removal of Pb(II) and Cu(II) from water [J].
Peng, XJ ;
Luan, ZK ;
Di, ZC ;
Zhang, ZG ;
Zhu, CL .
CARBON, 2005, 43 (04) :880-883
[22]  
Premamoy G., 1999, EUR POLYM J, V35, P699
[23]   Spontaneous coating of carbon nanotubes with an ultrathin polypyrrole layer [J].
Pumera, Martin ;
Smid, Bretislav ;
Peng, Xinsheng ;
Golberg, Dmitri ;
Tang, Jie ;
Ichinose, Izumi .
CHEMISTRY-A EUROPEAN JOURNAL, 2007, 13 (27) :7644-7649
[24]   Magnetic loading of carbon nanotube/nano-Fe3O4 composite for electrochemical sensing [J].
Qu, Song ;
Wang, Joseph ;
Kong, Jilie ;
Yang, Pengyuan ;
Chen, Gang .
TALANTA, 2007, 71 (03) :1096-1102
[25]   Soluble self-aligned carbon nanotube/polyaniline composites [J].
Sainz, R ;
Benito, AM ;
Martínez, MT ;
Galindo, JF ;
Sotres, J ;
Baró, AM ;
Corraze, B ;
Chauvet, O ;
Maser, WK .
ADVANCED MATERIALS, 2005, 17 (03) :278-+
[26]   Carbon nanotube/polysulfone composite screen-printed electrochemical enzyme biosensors [J].
Sanchez, Samuel ;
Pumera, Martin ;
Cabruja, Enric ;
Fabregas, Esteve .
ANALYST, 2007, 132 (02) :142-147
[27]   Carbon-nanotube based electrochemical biosensors: A review [J].
Wang, J .
ELECTROANALYSIS, 2005, 17 (01) :7-14
[28]   Carbon nanotube/teflon composite electrochemical sensors and biosensors [J].
Wang, J ;
Musameh, M .
ANALYTICAL CHEMISTRY, 2003, 75 (09) :2075-2079
[29]   Carbon-nanotube/copper composite electrodes for capillary electrophoresis microchip detection of carbohydrates [J].
Wang, J ;
Chen, G ;
Wang, M ;
Chatrathi, MP .
ANALYST, 2004, 129 (06) :512-515
[30]   Polyaniline nanotubes doped with sulfonated carbon nanotubes made via a self-assembly process [J].
Wei, ZX ;
Wan, MX ;
Lin, T ;
Dai, LM .
ADVANCED MATERIALS, 2003, 15 (02) :136-+