Synthesis, Reactivity, and Electronic Properties of 6,6-Dicyanofulvenes

被引：55

作者：

Andrew, Trisha L. ^{[1
]}

Cox, Jason R. ^{[1
]}

Swager, Timothy M. ^{[1
]}

机构：

[1] MIT, Dept Chem, Cambridge, MA 02139 USA

来源：

ORGANIC LETTERS | 2010年 / 12卷 / 22期

基金：

美国国家科学基金会;

关键词：

FIELD-EFFECT TRANSISTORS; THIN-FILM TRANSISTORS; N-CHANNEL; HIGH-PERFORMANCE; BUILDING-BLOCKS; BAND-GAP; SEMICONDUCTORS; DESIGN; MICROSTRUCTURE; DERIVATIVES;

D O I：

10.1021/ol102384k

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A series of 6,6-dicyanofulvene derivatives are synthesized starting from masked, dimeric, or monomeric cyclopentadienones. The reactivities of 6,6-dicyanofulvenes relative to their parent cyclopentadienones are discussed. 6,6-Dicyanofulvenes are capable of undergoing two consecutive, reversible, one-electron reductions and are presented as potential n-type small molecules.

引用

收藏

页码：5302 / 5305

页数：4

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