Exo-metal coordination by a tricyclic [{P(μ-N-2-NC5H4)}2(μ-O)]2 dimer in [{P(μ-N-2-NC5H4)}2(μ-O)]2{CuCl•(C5H5N)2}4 {2-NC5H4=2-pyridyl, C5H5N=pyridine)

被引：28

作者：

Bond, AD

Doyle, EL

García, F

Kowenicki, RA

McPartlin, M

Riera, L

Wright, DS

机构：

[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

[2] Univ N London, Sch Chem, London N7 8DB, England

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 24期

关键词：

D O I：

10.1039/b309842g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The in situ reaction of the phosphazane dimer [ClP(mu-N-2-NC5H4)](2) (2) with CuCl in the presence Of C5H5N/H2O gives the title complex [{P(mu-N-2-NC5H4)}(2)(mu-O)](2)(CuCl.(C5H5N)(2))(4) (1), containing a tricyclic [(P(mu-N-2-NC5H4)}2(mu-O)](2) ligand which is isoelectronic with species of the type [{P(mu-NR))(2)NR](2).

引用

页码：2990 / 2991

页数：2

共 20 条

[1] CONFORMATIONAL ISOMERISM IN MIXED-LIGAND COMPLEXES OF 2,2'-BIPYRIDINE AND TRIPHENYLPHOSPHINE WITH COPPER(I) HALIDES [J].

BARRON, PF ;

ENGELHARDT, LM ;

HEALY, PC ;

KILDEA, JD ;

WHITE, AH .

INORGANIC CHEMISTRY, 1988, 27 (10) :1829-1834

[2]

Bashall A, 2002, CHEM-EUR J, V8, P3377, DOI 10.1002/1521-3765(20020802)8:15<3377::AID-CHEM3377>3.0.CO

[3]

2-5

[4]

Bashall A, 2002, CHEM-EUR J, V8, P5723, DOI 10.1002/1521-3765(20021216)8:24<5723::AID-CHEM5723>3.0.CO

[5]

2-D

[6] The tetrameric macrocycle [{P(μ-N-tBu)}2NH]4 [J].

Bashall, A ;

Doyle, EL ;

Tubb, C ;

Kidd, SJ ;

McPartlin, M ;

Woods, AD ;

Wright, DS .

CHEMICAL COMMUNICATIONS, 2001, (24) :2542-2543

[7] {Li[P(NtBu)2]}4.0.25P4(NtBu)6:: Solvent and substituent effects on the structures and reactivity of 1,3-diaza-2-phosphaallyllithium complexes [J].

Brask, JK ;

Chivers, T ;

Krahn, ML ;

Parvez, M .

INORGANIC CHEMISTRY, 1999, 38 (02) :290-295

[8]

GONGDU Z, 1987, ACTA PHYS-CHIM SIN, V3, P573

[9] P4(N-I-C3H7)6, A P4X6 MOLECULE WITH AND WITHOUT ADAMANTANE STRUCTURE [J].

SCHERER, OJ ;

ANDRES, K ;

KRUGER, C ;

TSAY, YH ;

WOLMERHAUSER, G .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1980, 19 (07) :571-572

[10] Chlorotripyridinecopper(I) [J].

Scholz, S ;

Lerner, HW ;

Bolte, M .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2002, 58 :m72-m73

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