Host-guest interactions: Design strategy and structure of an unusual cobalt cage that encapsulates a tetrafluoroborate anion

被引：94

作者：

Amouri, H

Mimassi, L

Rager, MN

Mann, BE

Guyard-Duhayon, C

Raehm, L

机构：

[1] Univ Paris 06, CNRS, UMR 7071, Lab Chim Inorgan & Mat Mol, F-75252 Paris, France

[2] Ecole Natl Super Chim Paris, NMR Serv, F-75231 Paris, France

[3] Univ Sheffield, Dept Chem, Sheffield S3 7HF, S Yorkshire, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 29期

关键词：

host-guest systems; boron; cage compounds; cobalt; supramolecular chemistry;

D O I：

10.1002/anie.200500786

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Stuck in the middle: Supramolecular host-guest cages of general formula [BF4C(RCN)2Co 2L4](BF4)3 with L being a di(benzimidazole)-1,4-phenylene derivative (R = Me, Et, Ph) have been prepared. An encapsulated BF4- anion (B yellow, F pale green; see structure) is locked firmly inside the cage and plays a pivotal role as a template around which the CoII ions (gray) and L ligands (ball-and-stick representation) self-assemble. © 2005 Wiley-VCH Verlag GmbH &. Co. KGaA.

引用

页码：4543 / 4546

页数：4

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