Electron charging and discharging effects of tungsten nanocrystals embedded in silicon dioxide for low-voltage nonvolatile memory technology

被引:37
作者
Chang, TC [1 ]
Liu, PT
Yan, ST
Sze, SM
机构
[1] Natl Sun Yat Sen Univ, Dept Phys, Kaohsiung, Taiwan
[2] Natl Sun Yat Sen Univ, Inst Electroopt Engn, Kaohsiung, Taiwan
[3] Natl Sun Yat Sen Univ, Ctr Nanosci & Nanotechnol, Kaohsiung 804, Taiwan
[4] Natl Nano Device Lab, Hsinchu 300, Taiwan
[5] Natl Chiao Tung Univ, Dept Photon & Display Inst, Hsinchu, Taiwan
[6] Natl Chiao Tung Univ, Inst Elect, Hsinchu 30039, Taiwan
关键词
D O I
10.1149/1.1859674
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Spherical and well-separated tungsten nanocrystals embedded in the SiO2 layer are demonstrated for the low-voltage nonvolatile memory device. The tungsten dots are formed, based on the thermal oxidation of the tungsten silicide, with a mean size and aerial density of 4.5 nm and 3.7 x 10(11)/ cm(2), respectively. A pronounced capacitance-voltage hysteresis is observed with a memory window of 0.95 V under the 3 V programming voltage. Also, the endurance of the memory device is not degraded up to 106 write/erase cycles. (C) 2005 The Electrochemical Society.
引用
收藏
页码:G71 / G73
页数:3
相关论文
共 17 条
[1]   Production of tungsten oxide coatings, via sol-gel processing of tungsten anion solutions [J].
Baker, AP ;
Hodgson, SNB ;
Edirisinghe, MJ .
SURFACE & COATINGS TECHNOLOGY, 2002, 153 (2-3) :184-193
[2]   W2Cl4(NR2)(2)(PR'(3))(2) molecules .6. New triply-bonded ditungsten complexes with bis(diphenylphosphino) methane or bis(diphenylphosphino) amine as a bridging ligand. Crystal structures of cis,cis-W2Cl4(NR2)(2)(dppm) (R=Et, Bu-n) and W2Cl3(NHCMe3)(2)(NH2CMe3)(PPh2NPOPh2) [J].
Cotton, FA ;
Dikarev, EV ;
Nawar, N ;
Wong, WY .
INORGANICA CHIMICA ACTA, 1997, 262 (01) :21-32
[3]   Nanocrystal nonvolatile memory devices [J].
De Blauwe, J .
IEEE TRANSACTIONS ON NANOTECHNOLOGY, 2002, 1 (01) :72-77
[4]   Oxynitride films formed by low energy NO+ implantation into silicon [J].
Diniz, JA ;
Tatsch, PJ ;
Pudenzi, MAA .
APPLIED PHYSICS LETTERS, 1996, 69 (15) :2214-2215
[5]   Structural and electrical properties of silicon dioxide layers with embedded germanium nanocrystals grown by molecular beam epitaxy [J].
Kanjilal, A ;
Hansen, JL ;
Gaiduk, P ;
Larsen, AN ;
Cherkashin, N ;
Claverie, A ;
Normand, P ;
Kapelanakis, E ;
Skarlatos, D ;
Tsoukalas, D .
APPLIED PHYSICS LETTERS, 2003, 82 (08) :1212-1214
[6]   MOS memory using germanium nanocrystals formed by thermal oxidation of Si1-xGex [J].
King, YC ;
King, TJ ;
Hu, CM .
INTERNATIONAL ELECTRON DEVICES MEETING 1998 - TECHNICAL DIGEST, 1998, :115-118
[7]   Charging effects in silicon nanocrystals within SiO2 layers, fabricated by chemical vapor deposition, oxidation, and annealing [J].
Kouvatsos, DN ;
Ioannou-Sougleridis, V ;
Nassiopoulou, AG .
APPLIED PHYSICS LETTERS, 2003, 82 (03) :397-399
[8]   GROWTH-RATE AND CHARACTERIZATION OF SILICON-OXIDE FILMS GROWN IN N2O ATMOSPHERE IN A RAPID THERMAL PROCESSOR [J].
LANGE, P ;
BERNT, H ;
HARTMANNSGRUBER, E ;
NAUMANN, F .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1994, 141 (01) :259-263
[9]   Metal nanocrystal memories - Part I: Device design and fabrication [J].
Liu, ZT ;
Lee, C ;
Narayanan, V ;
Pei, G ;
Kan, EC .
IEEE TRANSACTIONS ON ELECTRON DEVICES, 2002, 49 (09) :1606-1613
[10]   Ultraclean two-stage aerosol reactor for production of oxide-passivated silicon nanoparticles for novel memory devices [J].
Ostraat, ML ;
De Blauwe, JW ;
Green, ML ;
Bell, LD ;
Atwater, HA ;
Flagan, RC .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2001, 148 (05) :G265-G270