Stereoselective self-assembly of atropoisomeric Pd(II) metallocycles induced by an aromatic guest

被引:21
作者
Abella, Dolores [1 ]
Blanco, Victor [1 ]
Pia, Elena [1 ]
Chas, Marcos [1 ]
Platas-Iglesias, Carlos [1 ]
Peinador, Carlos [1 ]
Quintela, Jose M. [1 ]
机构
[1] Univ A Coruna, Dept Quim Fundamental, Fac Ciencias, La Coruna 15071, Spain
关键词
D O I
10.1039/b802213e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new dinuclear Pd(II) metallocycle consisting of a 4,4'- bipyridin-1- ium ligand with a quinoline moiety was self-assembled in aqueous solution with the aid of template molecules; the situation found in solution in which both syn and anti or only the anti atropoisomers are observed strongly relies on the intermolecular host-guest interactions.
引用
收藏
页码:2879 / 2881
页数:3
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