Identification of the native vacancy defects in both sublattices of ZnSxSe1-x by positron annihilation

被引:48
作者
Saarinen, K [1 ]
Laine, T [1 ]
Skog, K [1 ]
Makinen, J [1 ]
Hautojarvi, P [1 ]
Rakennus, K [1 ]
Uusimaa, P [1 ]
Salokatve, A [1 ]
Pessa, M [1 ]
机构
[1] TAMPERE UNIV TECHNOL, DEPT PHYS, TAMPERE 33101, FINLAND
关键词
D O I
10.1103/PhysRevLett.77.3407
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We show how positron annihilation can distinguish vacancies in the different sublattices of a binary compound by performing experiments in ZnS(x)Se(1-x)layers. We identify the Se vacancies (V-Se) in N-doped and the Zn vacancies (V-zn) in Cl-doped material by the shape of the core electron momentum distribution. The charge of the defect involving V-Se is neutral or negative in p-type ZnSxSe1-x, suggesting that Vs, is complexed with an acceptor. The concentration of the Vs, complexes is high (greater than or equal to 10(18) cm(-3)), indicating that their role is important in the electrical compensation, of p-type ZnSxSe1-x.
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页码:3407 / 3410
页数:4
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