Catalytic alkylation of aromatic amines with styrene in the presence of cationic rhodium complexes and acid

被引：73

作者：

Beller, M

Thiel, OR

Trauthwein, H

机构：

[1] Univ Rostock eV, Inst Organ Katalyseforsch, D-18055 Rostock, Germany

[2] Tech Univ Munich, Inst Anorgan Chem, D-85747 Garching, Germany

[3] Aventis, D-65926 Frankfurt, Germany

来源：

SYNLETT | 1999年 / 02期

关键词：

catalysis; alkylation; amination; rhodium; Friedel-Crafts alkylation;

D O I：

10.1055/s-1999-2579

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The first transition metal-catalyzed Friedel-Crafts alkylation of aromatic amines with styrene is reported. ortho-alkylation of anilines occurs using catalytic amounts of [Rh(cod)(2)]BF4/4 PPh3 and HBF4.

引用

页码：243 / 245

页数：3

共 21 条

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