Conjugate addition of aryl boronic acids to enones catalyzed by cationic palladium(II)-phosphane complexes

被引：171

作者：

Nishikata, T ^{[1
]}

Yamamoto, Y ^{[1
]}

Miyaura, N ^{[1
]}

机构：

[1] Hokkaido Univ, Grad Sch Engn, Div Mol Chem, Sapporo, Hokkaido 0608628, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 24期

关键词：

boron; enones; Michael addition; palladium; synthetic methods;

D O I：

10.1002/anie.200350888

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A cationic palladium complex was found to be an efficient catalyst for the 1,4-addition of aryl boronic acids to enones at room temperature (see scheme; X= ClO4, OTf, BF4, PF6, or SbF6); Tf=trifluoromethanesulfonyl).

引用

页码：2768 / 2770

页数：3

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