The first highly stable homochiral olefin-copper(I) 2D coordination polymer grid based on quinine as building block

被引：56

作者：

Qu, ZR

Chen, ZF ^{[1
]}

Zhang, J

Xiong, RG

Abrahams, BF

Xue, ZL

机构：

[1] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China

[2] Univ Melbourne, Sch Chem, Parkville, Vic 3052, Australia

[3] Univ Tennessee, Dept Chem, Knoxville, TN 37996 USA

来源：

ORGANOMETALLICS | 2003年 / 22卷 / 14期

关键词：

D O I：

10.1021/om030134w

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Solvothermal reactions of quinine with (CuCl)-Cl-I or (CuBr)-Br-I yield the two highly stable homochiral copper(I)-olefin coordination polymers Cu8Cl10(H-quinine)(2) (1) and Cu8Br10(H-quinine)(2) (2), respectively, in which both 1 and 2 are 2D layered networks and are isostructural. The electric hysteresis loop of 1 clearly shows it displays a typical ferroelectric behavior with a remanent polarization (Pr) of ca. 0.12 muC cm(-2).

引用

页码：2814 / 2816

页数：3

共 64 条

[51] Two chiral coordination polymers: Preparation and X-ray structures of mono(4-sulfo-L-phenylalanine)(diaqua) zinc(II) and copper(II) complexes [J].