Formation of secondary ozonides in the gas-phase ozonolysis of simple alkenes

被引：70

作者：

Neeb, P ^{[1
]}

Horie, O ^{[1
]}

Moortgat, GK ^{[1
]}

机构：

[1] MAX PLANCK INST CHEM,DIV ATMOSPHER CHEM,D-55020 MAINZ,GERMANY

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 52期

关键词：

D O I：

10.1016/S0040-4039(97)82946-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Secondary propene ozonide and isobutene ozonide were formed in the gas-phase ozonolysis of ethene with added acetaldehyde and acetone, respectively. Combined with the formation of hydroperoxymethyl formate and methoxymethyl hydroperoxide in the ethene-ozone reaction system in the presence of HCOOH and CH3OH, respectively, formation of the secondary ozonides reveals a close similarity between the gas-phase and the liquid-phase ozonolysis of alkenes. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：9297 / 9300

页数：4

共 20 条

[1]

[Anonymous], 1975, Angew. Chem, DOI [10.1002/ange.19750872104, DOI 10.1002/ANGE.19750872104]

[2] GAS-PHASE TROPOSPHERIC CHEMISTRY OF ORGANIC-COMPOUNDS - A REVIEW [J].

ATKINSON, R .

ATMOSPHERIC ENVIRONMENT PART A-GENERAL TOPICS, 1990, 24 (01) :1-41

[3]

Bailey P. S., 1978, OZONATION ORGANIC CH, V1

[4] A CCSD(T) INVESTIGATION OF CARBONYL OXIDE AND DIOXIRANE - EQUILIBRIUM GEOMETRIES, DIPOLE-MOMENTS, INFRARED-SPECTRA, HEATS OF FORMATION AND ISOMERIZATION ENERGIES [J].

CREMER, D ;

GAUSS, J ;

KRAKA, E ;

STANTON, JF ;

BARTLETT, RJ .

CHEMICAL PHYSICS LETTERS, 1993, 209 (5-6) :547-556

[5] MECHANISM OF OZONOLYSIS [J].

CRIEGEE, R .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1975, 14 (11) :745-752

[6] Observation of secondary 2-butene ozonide in the ozonation of trans-2-butene in the gas phase [J].

Fajgar, R ;

Vitek, J ;

Haas, Y ;

Pola, J .

TETRAHEDRON LETTERS, 1996, 37 (19) :3391-3394

[7] MECHANISM OF THE OZONOLYSIS OF ETHYLENE IN THE LIQUID-PHASE [J].

FONG, GD ;

KUCZKOWSKI, RL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (14) :4763-4768

[8] Formation of OH radicals in the gas phase ozonolysis of alkenes, the unexpected role of carbonyl oxides [J].

Gutbrod, R ;

Schindler, RN ;

Kraka, E ;

Cremer, D .

CHEMICAL PHYSICS LETTERS, 1996, 252 (3-4) :221-229

[9] REACTIONS OF CRIEGEE INTERMEDIATES IN THE GAS-PHASE [J].

HATAKEYAMA, S ;

AKIMOTO, H .

RESEARCH ON CHEMICAL INTERMEDIATES, 1994, 20 (3-5) :503-524

[10]

HATAKEYAMA S, UNPUB

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