Crystal structures of the coordination polymers formed between 1,2-bis(3′-pyridyl)ethyne and silver(I) trifluoromethanesulfonate

被引：7

作者：

Bosch, E ^{[1
]}

Barnes, CL

机构：

[1] SW Missouri State Univ, Dept Chem, Springfield, MO 65804 USA

[2] Univ Missouri, Dept Chem, Columbia, MO 65211 USA

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2005年 / 58卷 / 12期

关键词：

silver(I); coordination polymer; 1,2-bis(3 '-pyridyl)ethyne;

D O I：

10.1080/00958970500092768

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of 1,2-bis(3'-pyridyl) ethyne with silver( I) trifluoromethanesulfonate yields two coordination networks. A one-dimensional double-stranded coordination polymer was formed in acetonitrile. The silver has a square-planar coordination geometry with weak coordination to one acetonitrile molecule and the triflate counter ion. The second network, formed in dichloromethane, is a complex three-dimensional network of interconnected one-dimensional zig-zag ribbons.

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页码：1021 / 1027

页数：7

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