A Highly Porous Metal-Organic Framework with Open Nickel Sites

被引：144

作者：

Gedrich, Kristina ^{[1
]}

Senkovska, Irena ^{[1
]}

Klein, Nicole ^{[1
]}

Stoeck, Ulrich ^{[1
]}

Henschel, Antje ^{[1
]}

Lohe, Martin R. ^{[1
]}

Baburin, Igor A. ^{[2
]}

Mueller, Uwe ^{[3
]}

Kaskel, Stefan ^{[1
]}

机构：

[1] Tech Univ Dresden, Dept Inorgan Chem, D-01069 Dresden, Germany

[2] Max Planck Inst Chem Phys Solids, D-01187 Dresden, Germany

[3] Helmholtz Zentrum Berlin Mat & Energie, BESSY MX Grp, Inst Soft Matter & Funct Mat, D-12489 Berlin, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 45期

关键词：

gas storage; metal-organic frameworks; nickel; open metal sites; supercritical drying; PRESSURE METHANE ADSORPTION; COORDINATION POLYMER; HYDROGEN STORAGE; BUILDING-BLOCKS; SURFACE-AREA; NANOPOROUS MATERIALS; CARBON-DIOXIDE; LARGE PORES; MICROPOROSITY; DIFFRACTION;

D O I：

10.1002/anie.201001735

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A healthy appetite: A new metal-organic framework (DUT-9; see picture) has an unprecedented topology that contains {Ni5(μ3-O) 2(CO2)6} clusters (green polyhedra; C-gray, O-red). DUT-9 has very high storage capacities for methane, hydrogen, and carbon dioxide because of the presence of open metal sites (marked by stars). © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：8489 / 8492

页数：4

共 59 条

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