Efficiency enhancement of Cu(In,Ga)Se2 solar cells due to post-deposition Na incorporation

被引:267
作者
Rudmann, D [1 ]
da Cunha, AF
Kaelin, M
Kurdesau, F
Zogg, H
Tiwari, AN
Bilger, G
机构
[1] ETH, Swiss Fed Inst Technol, Solid State Phys Lab, Thin Film Phys Grp, CH-8005 Zurich, Switzerland
[2] Univ Stuttgart, Inst Phys Elect, D-70569 Stuttgart, Germany
[3] Loughborough Univ Technol, Dept Elect & Elect Engn, Loughborough LE11 3TU, Leics, England
[4] Univ Aveiro, Dept Fis, P-3810193 Aveiro, Portugal
关键词
D O I
10.1063/1.1646758
中图分类号
O59 [应用物理学];
学科分类号
摘要
Cu(In,Ga)Se-2 (CIGS) absorber layers for thin-film solar cells were grown without sodium. Na was diffused into some of the absorbers after growth, which led to strongly improved device performance compared with Na-free cells. Efficiencies of 13.3% and 14.4% were achieved at substrate temperatures as low as 400 and 450degreesC, respectively. With the post-deposition treatment, the effects of Na on CIGS growth are excluded, and most of the Na is expected to reside at grain boundaries. The dominating cause for Na-induced device improvements might be passivation of grain boundaries. (C) 2004 American Institute of Physics.
引用
收藏
页码:1129 / 1131
页数:3
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