Inter- and intramolecular radical couplings of ene-ynes or halo-alkenes promoted by an InCl3/MeONa/Ph2SiH2 system

被引：37

作者：

Hayashi, N ^{[1
]}

Shibata, I ^{[1
]}

Baba, A ^{[1
]}

机构：

[1] Osaka Univ, Grad Sch Engn, Ctr Atom & Mol Technol, Dept Appl Chem, Suita, Osaka 5650871, Japan

来源：

ORGANIC LETTERS | 2005年 / 7卷 / 14期

关键词：

D O I：

10.1021/ol051114o

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An effective generation of indium hydride (HInCl2) under nonacidic conditions is achieved by transmetalation between Ph2SiH2 and InCl2OMe. The presented system achieves the titled coupling reactions in a radical manner. In particular, the nonacidic character enables the applications to acid-sensitive inter- and intramolecular ene-yne couplings.

引用

页码：3093 / 3096

页数：4

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