Dynamic oxide interfaces by microscopic techniques at high resolutions

被引：17

作者：

Iwasawa, Y ^{[1
]}

机构：

[1] Univ Tokyo, Grad Sch Sci, Dept Chem, Bunkyo Ku, Tokyo 113, Japan

来源：

SURFACE SCIENCE | 1998年 / 402卷 / 1-3期

关键词：

atom-resolved images; formate ions; in-situ observation of adsorbed molecules and surface reactions; non-contact atomic force microscopy (AFM); oxide surfaces; pyridine; scanning tunneling microscopy (STM);

D O I：

10.1016/S0039-6028(98)00016-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This paper attempts to extend our previous studies on the structure of TiO2(110)-(1 x 1) surface, the anisotropic transport of formate anions on the surface, and the dynamic visualization of surface/gas-phase reaction at 800 K. The paper also reports the first atom-resolved non-contact AFM image of TiO2(110)-(1 x 1), which reveals protruding bridge-oxygen atoms ordered in a (1 x 1) periodicity and point defects of the oxygen atoms on terraces. STM also resolved and traced the individual pyridine molecules that are mobile on the oxide surface. Site-specific adsorption of pyridine on the particular step sites highly oriented toward the [001] axis on TiO2(110)-(1 x 1) was also atomically resolved. (C) 1998 Elsevier Science B.V. All rights reserved.

引用

页码：8 / 19

页数：12

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