Dramatically Different Conductivity Properties of Metal-Organic Framework Polymorphs of Tl(TCNQ): An Unexpected Room-Temperature Crystal-to-Crystal Phase Transition

被引：104

作者：

Avendano, Carolina ^{[1
]}

Zhang, Zhongyue ^{[1
]}

Ota, Akira ^{[1
]}

Zhao, Hanhua ^{[1
]}

Dunbar, Kim R. ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 29期

基金：

美国国家科学基金会;

关键词：

main group elements; metal-organic frameworks; polymorphism; semiconductors; thallium; RADICAL-ION SALTS; TETRATHIAFULVALENE-CHLORANIL; DEUTERATED CU(DCNQI)(2); THIN-FILMS; COMPLEX; TCNQ; TETRACYANOQUINODIMETHANE; (EDO-TTF)(2)PF6; CHEMISTRY; PRESSURE;

D O I：

10.1002/anie.201100372

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Just add water: Tl(TCNQ) polymorphs with very different charge-transport properties have been isolated, one of which undergoes a remarkable crystal-to-crystal phase transition to the second phase when exposed to ambient water vapor (see picture; TCNQ=tetracyanoquinodimethane). Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：6543 / 6547

页数：5

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