Synthesis and structure of the highly chlorinated [60]fullerene C60Cl30 with a drum-shaped carbon cage

被引：123

作者：

Troshin, PA ^{[1
]}

Lyubovskaya, RN

Ioffe, IN

Shustova, NB

Kemnitz, E

Troyanov, SZ

机构：

[1] Russian Acad Sci, Inst Problems Chem Phys, Moscow 142432, Russia

[2] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119992, Russia

[3] Humboldt Univ, Inst Chem, D-12489 Berlin, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 02期

关键词：

chlorination; density functional calculations; fullerenes; structure elucidation;

D O I：

10.1002/anie.200461531

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Chlorination of C60 with SbCl5, ICl, or ICl 3 at 220-250 °C gives the highly chlorinated fullerene C 60Cl30. The carbon cage of the C60Cl 30 molecule has a unique cylindrical shape (see picture), composed of two aromatic six-membered rings located opposite each other and one equatorial aromatic 18π trannulene belt. DFT calculations suggest that C 60Cl30 is the final product of [60]fullerene chlorination.

引用

页码：234 / 237

页数：4

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