Intrinsic pyramidal nitrogen of N-sulfonylamides

被引：36

作者：

Ohwada, T

Okamoto, I

Shudo, K

Yamaguchi, K

机构：

[1] Univ Tokyo, Grad Sch Pharmaceut Sci, Bunkyo Ku, Tokyo 113, Japan

[2] Chiba Univ, Ctr Chem Anal, Inage Ku, Chiba 263, Japan

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 43期

关键词：

D O I：

10.1016/S0040-4039(98)01746-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The pyramidalization of the nitrogen in sulfonamides of 7-azabicyclo[2.2.1]heptane is enhanced in the solid state as compared with the corresponding monocyclic sulfonamides of pyrrolidine and 3-pyrroline. We postulate a general structural motif of pyramidal nitrogen in sulfonamides. (C) 1998 Elsevier Science Ltd. All rights reserved.

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页码：7877 / 7880

页数：4

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