A nanoporous metal-organic framework with accessible Cu2+ sites for the catalytic Henry reaction

被引：96

作者：

Shi, Lian-Xu ^{[1
]}

Wu, Chuan-De ^{[1
]}

机构：

[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Zhejiang, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 10期

关键词：

NITROALDOL REACTION; POSTSYNTHETIC MODIFICATION; COMPLEX; STORAGE; NETWORK; POLYMER; DESIGN; ACID;

D O I：

10.1039/c0cc05074a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel 3D porous metal-organic framework containing 1D nanoscale opening channels was constructed from two kinds of pyridine carboxylates and copper(II) nodes with reachable copper sites located in the channel walls, which can be subsequently used to prompt the Henry reaction of benzaldehydes and nitroalkanes with remarkable catalytic activity compared with homogeneous copper cations.

引用

页码：2928 / 2930

页数：3

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