Synthesis, Structure, and Application of Self-Assembled Copper(II) Aqua Complex by H-Bonding for Acceleration of the Nitroaldol Reaction on Water

被引：47

作者：

Jammi, Suribabu ^{[1
]}

Ali, Md Ashif ^{[1
]}

Sakthivel, Sekarpandi ^{[1
]}

Rout, Laxmidhar ^{[1
]}

Punniyamurthy, Tharmalingam ^{[1
]}

机构：

[1] Indian Inst Technol Guwahati, Dept Chem, Gauhati 781039, India

来源：

CHEMISTRY-AN ASIAN JOURNAL | 2009年 / 4卷 / 02期

关键词：

C-C coupling; heterogeneous catalysis; hydrogen bonds; nitroaldol reaction; self-assembly; ASYMMETRIC HENRY REACTION; CONJUGATED NITROALKENES; AQUEOUS-MEDIA; EFFICIENT SYNTHESIS; ORGANIC-COMPOUNDS; ALDOL REACTION; CATALYSIS; CHLORIDE; AMINOALCOHOLS; ADDITIVES;

D O I：

10.1002/asia.200800339

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Copper(II) aqua complex 1 has been prepared in a one-pot synthesis. The single crystal X-ray analysis showed that the complex is self-assembled through aqua ligands by H-bond interactions and the copper(II) atoms are pentacoordinated with square pyramidal geometry. Complex 1 has been studied for the acceleration of the nitroalodol reaction on water. It is a clean technological process and the catalyst can be recycled without loss of activity.

引用

页码：314 / 320

页数：7

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