Synthesis, Structure and Catalysis of Tetranuclear Copper(II) Open Cubane for Henry Reaction on Water

被引：31

作者：

Jammi, Suribabu ^{[1
]}

Punniyamurthy, Tharmalingam ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Gauhati 781039, India

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2009年 / 17期

关键词：

C-C bond formation; Copper; Henry reaction; Heterogeneous catalysis; Water; ASYMMETRIC NITROALDOL REACTION; AQUEOUS-MEDIA; MOLECULAR-STRUCTURE; MAGNETIC-PROPERTIES; CRYSTAL-STRUCTURE; ORGANIC-COMPOUNDS; COMPLEX; OXIDATION; BEHAVIOR; CLUSTER;

D O I：

10.1002/ejic.200900141

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The copper(II) open cubane 1 has been synthesized and its structure determined. It is insoluble in water and efficiently catalyzes the Henry reaction with high yield. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

引用

页码：2508 / 2511

页数：4

共 67 条

[1] Practical asymmetric henry reaction catalyzed by a chiral Diamine-Cu(OAc)2 complex [J].

Arai, Takayoshi ;

Watanabe, Masahiko ;

Yanagisawa, Akira .

ORGANIC LETTERS, 2007, 9 (18) :3595-3597

[2] Resonant magnetization tunneling in the trigonal pyramidal Mn(IV)Mn-3(III) complex [Mn4O3Cl(O2CCH3)3(dbm)3] [J].

Aubin, SMJ ;

Dilley, NR ;

Pardi, L ;

Krzystek, J ;

Wemple, MW ;

Brunel, LC ;

Maple, MB ;

Christou, G ;

Hendrickson, DN .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (20) :4991-5004

[3] Nitroaldol reaction in aqueous media: An important improvement of the Henry reaction [J].

Ballini, R ;

Bosica, G .

JOURNAL OF ORGANIC CHEMISTRY, 1997, 62 (02) :425-427

[4] Recoverable PEG-supported copper catalyst for highly stereocontrolled nitroaldol condensation [J].

Bandini, Marco ;

Benaglia, Maurizio ;

Sinisi, Riccardo ;

Tommasi, Simona ;

Umani-Ronchi, Achille .

ORGANIC LETTERS, 2007, 9 (11) :2151-2153

[5] Highly enantioselective nitroaldol reaction catalyzed by new chiral copper complexes [J].

Bandini, Marco ;

Piccinelli, Fabio ;

Tommasi, Simona ;

Umani-Ronchi, Achille ;

Ventrici, Caterina .

CHEMICAL COMMUNICATIONS, 2007, (06) :616-618

[6] Iron-sulfur clusters: Nature's modular, multipurpose structures [J].

Beinert, H ;

Holm, RH ;

Munck, E .

SCIENCE, 1997, 277 (5326) :653-659

[7]

BERG JM, 1982, IRON SULFUR PROTEINS, V4, pCH1

[8] Protonated chiral catalysts: Versatile tools for asymmetric synthesis [J].

Bolm, C ;

Rantanen, T ;

Schiffers, I ;

Zani, L .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (12) :1758-1763

[9] Catalytic asymmetric Henry reaction [J].

Boruwa, Joshodeep ;

Gogoi, Naminita ;

Saikia, Partha Pratim ;

Barua, Nabin C. .

TETRAHEDRON-ASYMMETRY, 2006, 17 (24) :3315-3326

[10] Determining the geometries of transition states by use of antihydrophohic additives in water [J].

Breslow, R .

ACCOUNTS OF CHEMICAL RESEARCH, 2004, 37 (07) :471-478

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