Towards creating reversible silicon-based composite anodes for lithium ion batteries

被引:13
作者
Dimov, N. [1 ]
Yoshio, M. [1 ]
机构
[1] Saga Univ, Dept Appl Chem, Saga 8408502, Japan
关键词
D O I
10.1016/j.jpowsour.2007.06.118
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A new inexpensive method aimed at distinguishing the forms in which Li+ remains irreversibly trapped within composite silicon-based anodes was suggested and tested. It includes a life-cycle test at a fixed degree of lithiation during the initial cycles. The integral capacity values obtained from the test were then correlated with the various chemical species of Li+ present in the electrodes after various cycle numbers in both charged and discharged states. Such a technique may provide a quantitative analytical tool for developing this type of electrode. (C) 2007 Published by Elsevier B.V.
引用
收藏
页码:607 / 612
页数:6
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