Electrodeposition of high-pressure-stable bcc phase bismuth flowerlike micro/nanocomposite architectures at room temperature without surfactant

被引：19

作者：

Liu, Xiang-Yang ^{[1
]}

Sun, Peng ^{[1
]}

Ren, Shan ^{[1
]}

Wen, Li-Shi ^{[1
]}

机构：

[1] Zhongshan Univ, Sch Phys Sci & Engn, State Key Lab Optoelect Mat & Technol, Guangzhou 510275, Peoples R China

来源：

ELECTROCHEMISTRY COMMUNICATIONS | 2008年 / 10卷 / 01期

关键词：

electrodeposition; high-pressure-stable phase; single crystal; flowerlike micro/nanocomposite architectures;

D O I：

10.1016/j.elecom.2007.11.013

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Three-dimensional (3D) bismuth flowerlike micro/nanocomposite architectures were successfully prepared on Cu substrates by electrochemical self-assembly in aqueous solution at room temperature. The morphology, crystal structure, and composition were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), transmission electron microscopy (TEM), and energy dispersive X-ray spectroscopy (EDS). Results show that the synthesized 3D architectures are built with dozens of two-dimensional (2D) single crystal nanoscaled petals, which are high-pressure-stable bcc phase Bi. The thickness of the 2D petals is about 60 nm. The effects of the concentration of Bi3+ ions and the electric potential gradient on the evolution of the Bi flowerlike micro/nanocomposite architectures are discussed. (C) 2007 Elsevier B.V. All rights reserved.

引用

页码：136 / 140

页数：5

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