Asymmetric Transfer Hydrogenation Catalyzed by Mesoporous MCM-41-Supported Chiral Ru-Complex

被引：10

作者：

Sarkar, Shaheen M. ^{[1
]}

Yusoff, Mashitah Mohd ^{[1
]}

Rahman, Md Lutfor ^{[1
]}

机构：

[1] Univ Malaysia Pahang, Fac Ind Sci & Technol, Gambang 26300, Kuantan, Malaysia

来源：

JOURNAL OF THE CHINESE CHEMICAL SOCIETY | 2015年 / 62卷 / 02期

关键词：

N-sulfonyldiamine; MCM-41; Immobilization; Asymmetric catalysis; Transfer hydrogenation; RUTHENIUM(II) COMPLEXES; TRANSFER REDUCTION; HETEROGENEOUS CATALYSTS; MOLECULAR-SIEVES; KETONES; LIGANDS; MCM-41; NANOCATALYSTS; NANOPARTICLES; SULFONAMIDES;

D O I：

10.1002/jccs.201400319

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

Chiral N-sulfonyldiamine was successfully anchored on mesoporous MCM-41 silica. The MCM-41-supported chiral N-sulfonyldiamine was used as an efficient heterogeneous chiral ligand in the asymmetric transfer hydrogenation of ketones. This heterogeneous system offered satisfactory enantioselectivities up to 94% with excellent conversions.

引用

页码：177 / 181

页数：5

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