Synthesis of biaryls by intramolecular radical transfer in phosphinates

被引:44
作者
Clive, DLJ [1 ]
Kang, SZ [1 ]
机构
[1] Univ Alberta, Dept Chem, Edmonton, AB T6G 2G2, Canada
关键词
D O I
10.1021/jo010371d
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Phosphinates 20a-35a give biaryls 20b-35b on heating with stannanes in the presence of AIBN. The process involves a radical ipso substitution on the migrating aryl ring.
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页码:6083 / 6091
页数:9
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