Design and formation of a large tetrahedral cluster using 1,1′-binaphthyl ligands

被引：53

作者：

Biros, Shannon M. ^{[1
]}

Yeh, Robert M. ^{[1
]}

Raymond, Kenneth N. ^{[1
]}

机构：

[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 32期

关键词：

chiral recognition; metal-ligand assembly; self-assembly; supramolecular chemistry;

D O I：

10.1002/anie.200801226

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Presented) Greater than 700 Å3 is the calculated interior volume of a novel [Ga4L6] cluster constructed with a derivatized 1,1′-binaphthyl ligand. Due to the size of the cavity, a guest molecule of suitable size and shape is employed to template the supramolecular assembly (see scheme). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：6062 / 6064

页数：3

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