Synthesis, characterization and photochromic studies of spirooxazine-containing 2,2'-bipyridine ligands and their rhenium(I) tricarbonyl complexes

被引：85

作者：

Ko, CC

Wu, LX

Wong, KMC

Zhu, NY

Yam, VWW

机构：

[1] Univ Hong Kong, Ctr Carbon Rich Mol & Nano Scale Met Based Mat Re, Dept Chem, Hong Kong, Hong Kong, Peoples R China

[2] Univ Hong Kong, HKU CAS Joint Lab New Mat, Hong Kong, Hong Kong, Peoples R China

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2004年 / 10卷 / 03期

关键词：

luminescence; N ligands; photochromism; rhenium; spirooxazine;

D O I：

10.1002/chem.200305485

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of spirooxazine-containing 2,2'-bipyridine ligands and their rhenium(I) tricarbonyl complexes has been designed and synthesized, and their photo-physical, photochromic and electrochemical properties have been studied. The X-ray crystal structures of two of the complexes have been determined. Detailed studies showed that the emission properties of the complexes could readily be switched through photochromic reactions.

引用

页码：766 / 776

页数：11

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