Synthesis of benzofulvenes by palladium-catalyzed cyclization of 1,2-dialkynylbenzenes

被引：41

作者：

Lee, Chia-Ying ^{[1
]}

Wu, Ming-Jung ^{[1
]}

机构：

[1] Kaohsiung Med Univ, Fac Med & Appl Chem, Kaohsiung, Taiwan

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2007年 / 2007卷 / 21期

关键词：

benzofulvenes; palladium; cyclization; enediynes;

D O I：

10.1002/ejoc.200601029

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A palladium-catalyzed cyclization of enediynes for the synthesis of benzofulvenes 2 in yields of 59-76% was accomplished by treatment of dialkynylbenzenes 1 with 5 mol-% of PdX2 and 3 equiv. of CuX2 in acetonitrile at 60 degrees C for 2 h. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007).

引用

页码：3463 / 3467

页数：5

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